Abstract
The applications of aromatic thioketones in the synthesis of five- to eight-membered heterocycles with a variable number of sulfur atoms are summarized. The importance of aromatic thioketones as ‘superdienophilic’ and ‘superdipolarophilic’ compounds is described in the light of the recent literature. The methods for the generation of reactive sulfur-containing intermediates with their possible applications toward sulfur heterocycles are also presented.
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