Abstract
5-hydroxymethylfurfural (HMF), as one of the top ten important platform chemicals, can be used to produce 2,5-furandicarboxylic acid (FDCA), 2,5-dimethyl furan (DMF), levulinic acid, and other chemicals. An environmentally friendly system for the synthesis of sulfonated carbon materials from discarded masks has been proposed. A series of mask-based solid acid catalysts (bMC-SO3H) were prepared by a simple two-step process. Mechanochemical pretreatment (ball milling) of waste mask and sulfonated group precursor, followed by thermal carbonization under nitrogen gas, were used to synthesize sulfonated porous carbon. The total acid amount of the prepared bMC-SO3H was measured by the Boehm method, which exhibited 1.2–5.3 mmol/g. The addition of the sulfonated group precursor in the mechanochemical treatment (ball milling) process caused intense structure fragmentation of the discarded masks. These sulfonated porous carbons (bMC(600)-SO3H) as solid acid catalysts achieved fructose conversion of 100% and HMF yield of 82.1% after 120 min at 95 °C in 1-butyl-3-methylimidazolium chloride. The bMC-SO3H could be reused five times, during which both the HMF yield and fructose conversion were stable. This work provides a strategy for the synthesis of sulfonated carbon from discarded masks and efficient catalyzed fructose upgrading to HMF.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.