Abstract
Kinetic runs of microgel-aldolase mediated reactions between dihydroxyacetone phosphate cyclohexylamine salt and D-glyceraldehydes were made in CH2CN, THF, DMF, DMSO and MeOH and aqueous-organic solution of these solvents at physiological temperature 37º. The same runs were effected between DHAP cyclohexylamine salt and non-natural aldehyde acceptors under similar conditions. Reaction was fastest in 1:3 DMSO/ H2O, faster than in aqueous medium the environment in which this enzyme normally operates. Preparation of a non-natural sugar using this system is related.Keywords: Microgel-aldolase, Kinetic physiological temperature, Natural acceptors, Non-natural acceptors.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
