Abstract
Synthesis of N-substituted aminopentanes based on the reaction of the amines with 1-brompentanes (n-and iso-structure) and amino (bis-amino) hydroxy compounds via opening reaction of epoxides with amines environmentally friendly practices in water medium has been developed. Structure of obtained compounds by elemental analysis and IR-, 1H and 13C NMR-spectroscopy were confirmed.
Highlights
Modern direction of chemistry and chemical technology includes the development of new, environmentally safe chemical processes
Synthesis of N-substituted aminopentanes based on the reaction of the amines with 1-brompentanes (n-and iso-structure) and amino hydroxy compounds via opening reaction of epoxides with amines environmentally friendly practices in water medium has been developed
Improvement general methods of synthesis based on the available raw materials in aqueous medium are very relevant [6,7,8]
Summary
Modern direction of chemistry and chemical technology includes the development of new, environmentally safe chemical processes. Substituted diamines were used for the synthesis of azacrown ethers [9], and polymers for special purposes [10], stable carbines [11], silylenes [12] and other stable ions. They are used as ligands in asymmetric synthesis of valuable synthetic and natural products [13] and for the preparation of complexes with metals such as magnesium, copper, silver, palladium and platinum. The antitum or properties of physiologically active complexes of platinum (II) with diamines have been studied in detail and are widely used in medical practice [14]
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