Abstract
Abstract A series of substituted [4] and [5]helicenes were synthesized in moderate to good yields by an Ir-catalyzed annulative coupling of biarylcarboxylic acid chlorides with internal alkynes, which involves facile C-H bond cleavage and decarbonylation. The double annulative coupling of 1,1′:5′,1′′-ternaphthalene-2,2′′-dicarboxylic acid dichloride with 4-octyne was also accomplished to give rise to an S-shaped double helicene. Unexpectedly, a π-extended benzofluoranthene-merged [5]helicene was constructed through the annulative coupling and the successive C(aryl)-C(aryl) bond forming reaction when 1,1′:4′,1′′-ternaphthalene-2,2′′-dicarboxylic acid dichloride was employed as the substrate. The crystal structure and the optical properties of the latter unique product were also investigated.
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