Synthesis of Submicron SSZ-13 with Tunable Acidity by the Seed-Assisted Method and Its Performance and Coking Behavior in the MTO Reaction.

Abstract

Submicron SSZ-13 with different acidities was synthesized successfully with the assistance of nanosized SSZ-13 seeds. The methanol-to-olefins (MTO) properties of submicron SSZ-13 were evaluated. The lifetime of submicron SSZ-13 was enhanced because of the crystal size reduction. The selectivity of light olefins was improved evidently at the early stage of the MTO reaction as the acidity density decreased. TG, GC–MS, and in situ UV/vis spectra were utilized to investigate coking behavior during the MTO reaction. It was found that the acidity density influences the nature and rate of coke formation. The majority of the hydrocarbon pool species over SSZ-13 with a low acidity density (125.2 μmol/g) were methylated benzene carbocations, while that over SSZ-13 with a high acidity density (330.2 μmol/g) were methylated naphthalene carbocations. The low acidity density of SSZ-13 can suppress the hydrogen transfer reaction and polyaromatic generation.