Synthesis of submicron ferrous oxalate from red mud with high Fenton catalytic performance on degradation of methylene blue.

Abstract

Ferrous oxalate dihydrate (FOD) can be used as a photo-Fenton catalyst with remarkable photo-Fenton catalytic and photocatalytic performances on organic pollutant degradation. Various reduction processes were compared in the current study to synthesize FODs from ferric oxalate solutionutilizing the iron source in alumina waste red mud (RM), including natural light exposure (NL-FOD), UV light irradiation (UV-FOD), and hydroxylamine hydrochloride hydrothermal method (HA-FOD). The FODs were characterized and employed as photo-Fenton catalysts for methylene blue (MB) degradation, and the effects of HA-FOD dosage, H2O2 dosage, MB concentration, and the initial pH were investigated. The results show that HA-FOD has submicron sizes and lower impurity contents with more rapid degradation rates and higher degradation efficiencies compared with the other two FOD products. When using 0.1g/L of each obtained FOD, 50mg/L of MB can be rapidly degraded by HA-FOD by 97.64% within 10min with 20mg/L of H2O2 at pH of 5.0, while NL-FOD and UV-FOD achieve 95.52% in 30min and 96.72% in 15min at the same conditions, respectively. Meanwhile, HA-FOD exhibits strong cyclic stability after two recycling experiments. Scavenger experiments reveal that the predominant reactive oxygen species responsible for MB degradation are hydroxyl radicals. These findings demonstrate that submicron FOD catalyst can be synthesized using hydroxylamine hydrochloride hydrothermal process from ferric oxalate solution with high photo-Fenton degradation efficiency and reduced reaction time for wastewater treatment. The study also provides a new pathway of efficient utilization for RM.