Abstract

Abstract In this work, walnut-like zeolite LZ-276 was synthesized by hydrothermal method without any template and evaluated by the oxidative carboxylation of styrene. The structural features and textural properties of the obtained catalyst sample were characterized by a series of characterization methods. The evaluation reaction, oxidative carboxylation of styrene, exhibited good catalytic efficiency under the synergistic effect of the walnut-like zeolite and KI. After exploring different reaction conditions, an ideal yield of styrene carbonate (77%) is obtained without preliminary synthesis and isolation of the intermediate styrene oxide. What is more considerable is that the catalytic activity such as the yield of styrene carbonate did not show significant reduction in several cycles of one-pot reaction.

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