Abstract
Two new compounds with the formula [R 2Sn(OC 10H 6CHNCH 2CH 2COO)] 2 where R = CH 3 or n-C 4H 9, have been synthesized. The crystal structure of the dimethyltin compound is reported along with 1H, 13C and IR spectroscopic data for both compounds. The centrosymmetric dimethyltin complex exhibits octahedral coordination for each tin atom. The tridentate ligand chelate meridionally via the phenolate oxygen, the imino nitrogen and one carboxylate oxygen atom. Two further trans positions in the tin coordination sphere are taken up by the two methyl groups while the apical (sixth) position is filled by a shared carboxylate oxygen atom from the other organotin unit.
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