Synthesis of stimuli-responsive pillararene-based supramolecular polymer materials for the detection and separation of metal ions

Abstract

A stimuli-responsive supramolecular polymer network (G-(CN)2⊂BXDSP5) with aggregation-induced emission (AIE) properties has been efficiently constructed by host–guest interactions between pillar[5]arene derivative BXDSP5 and a homoditopic guest G-(CN)2, which shows not only excellent fluorescence properties due to the AIE effect but also desirable ion-sensing abilities in both solution and solid states, holding great potential in the applicable fluorescence detection for Fe3+. The resultant G-(CN)2⊂BXDSP5 can be transformed into supramolecular polymer gel at high concentration via multiple noncovalent interactions, showing multi-stimuli-responsiveness in response to temperature change, mechanical force, and competitive agent. Meanwhile, the xerogel of supramolecular polymer material has been successfully used to remove Fe3+ from water with high adsorption efficiency. In addition, an ion-responsive film based on supramolecular polymer has also been developed, which can serve as a practical and convenient fluorescence test kit for detecting Fe3+.