Synthesis of some new distyrylbenzene derivatives using immobilized Pd on an NHC-functionalized MIL-101(Cr) catalyst: photophysical property evaluation, DFT and TD-DFT calculations.

Esmaeil Niknam,Farhad Panahi,Maryam Heydari Dokoohaki,Ali Mahmoodi,Amin Reza Zolghadr,Ali Khalafi-Nezhad

doi:10.1039/d1ra00457c

Esmaeil Niknam, Farhad Panahi + Show 4 more

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https://doi.org/10.1039/d1ra00457c

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Abstract

In this study the catalytic application of a heterogeneous Pd-catalyst system based on metal organic framework [Pd–NHC–MIL-101(Cr)] was investigated in the synthesis of distyrylbenzene derivatives using the Heck reaction. The Pd–NHC–MIL-101(Cr) catalyst showed high efficiency in the synthesis of these π-conjugated materials and products were obtained in high yields with low Pd-contamination based on ICP analysis. The photophysical behaviors for some of the synthesized distyrylbenzene derivatives were evaluated. The DFT and TD-DFT methods were employed to determine the optimized molecular geometry, band gap energy, and the electronic absorption and emission wavelengths of the new synthesized donor–π–acceptor (D–π–A) molecules in the gas phase and in various solvents using the chemical model B3LYP/6-31+G(d,p) level of theory.

Highlights

The synthesis of uorescent compounds to be used in organic light emitting diodes (OLEDs),[1,2,3,4,5] solar cells,[6,7] organic eld effect transistors (OFETs),[8,9] sensing,[10,11,12] and uorescent probes[13,14,15,16] is highly considered
In this study the catalytic application of a heterogeneous Pd-catalyst system based on metal organic framework [Pd–NHC–MIL-101(Cr)] was investigated in the synthesis of distyrylbenzene derivatives using the Heck reaction
The Pd–NHC–MIL-101(Cr) catalyst system showed remarkable catalytic activity in the Heck reaction[51] and in order to further show its utility in organic synthesis we investigate its applicability in the synthesis of distyrylbenzenes (DSBs)

Summary

Introduction

The synthesis of uorescent compounds to be used in organic light emitting diodes (OLEDs),[1,2,3,4,5] solar cells,[6,7] organic eld effect transistors (OFETs),[8,9] sensing,[10,11,12] and uorescent probes[13,14,15,16] is highly considered. The Pd–NHC–MIL-101(Cr) catalyst showed high efficiency in the synthesis of these p-conjugated materials and products were obtained in high yields with low Pd-contamination based on ICP analysis.

Results

Conclusion