Synthesis of soluble branched polyimides derived from an ABB′ monomer

Abstract

AbstractA novel ABB′ monomer, an isomeric mixture of 4‐[4‐(2,4‐diaminophenoxy)phenoxy]phthalic acid 2‐methyl ester, was successfully prepared. The direct polycondensation of the ABB′ monomer was carried out to form polyamic acid monomethyl ester as a precursor with an inherent viscosity of 0.30 dL/g and a number‐average molecular weight of 12,000. The degree of branching of the precursor, determined by 1H NMR, was 0.07. The low degree of branching was caused by the differences in the reactivities of the amino groups. The shape factor was calculated to be 0.72. End‐modified reactions with acetyl chloride, benzoyl chloride, and phthalic anhydride were carried out. After the chemical imidization of the end‐modified precursors, end‐modified polyimides were successfully prepared. The end‐modified polyimides were soluble in dimethyl sulfoxide, dimethylformamide (DMF), and N‐methyl‐2‐pyrrolidinone. On the basis of thermogravimetry and differential scanning calorimetry measurements of the polyimides, the 5 wt % thermal loss temperatures were determined to be 400–520 °C, and the glass‐transition temperatures were determined to be 200–258 °C. According to the X‐ray diffraction measurements, the end‐modified polyimides were amorphous. A strong but brittle film was prepared from an acetamide end‐modified polyimide solution, via casting from a DMF solution, with a tensile strength of 46 MPa, an elongation at break of 4%, and a modulus of 1.3 GPa. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3200–3211, 2004