Abstract
AbstractA ruthenium complex with a chiral arene ligand [(camphor–arene)RuCl2]2 was synthesized by the reaction of RuCl3·nH2O with a chiral diene which was obtained from natural camphor in three steps. This complex catalyzed the asymmetric hydrogenation of acetophenone (64–85% ee), but decomposed in catalytic reactions involving C–H activation of 2-phenylpyridine or benzoic acid derivatives.
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