Abstract
AbstractA double‐headed initiator was synthesized yielding two functional groups for the initiation of the nickel mediated ring‐opening polymerization of γ‐benzyl‐L‐glutamate‐N‐carboxyanhydride and controlled radical polymerization of vinyl monomers via ATRP or NMP. Well‐defined block copolymers combining polypeptides and synthetic polymers were obtained.
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