Abstract

The ribbon-like nanopolymers were prepared by the crosslinking reaction of poly (α-methylstyrene)-block-poly (4-vinylpyridine) (PMS-block-P4VP) diblock copolymer films exhibiting P4VP cylindrical microdomains, with the vapour of 1, 4-dibromobutane in the solid state. It was indicated by transmission electron microscopy (TEM) and small-angle X-ray scattering (SAXS) that these crosslinked products had a structure of ribbon-like nanopolymers.

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