Abstract

In this paper, a methodology for systematically integrating the synthesis of combined heat, mass, and regeneration exchange networks with solar thermal is presented. The process considered involves the removal of ammonia from ammonia-rich gaseous streams using water-based solvents as the mass separating agent (MSA) and subsequent regeneration of the ammonia-rich MSA stream using steam stripping. A composite superstructure, which comprises the stage-wise superstructure for the synthesis of the heat exchanger network subsystem, primary mass exchanger network subsystem, regeneration subsystem and integrated solar thermal with periodic heat storage, is developed. In order to simplify the modelling of the unpredictable availability of solar thermal energy within the composite superstructure, a multi-periodic synthesis approach is adopted. Sensitivity analysis was performed to establish the price at which solar thermal is favoured over fossil-derived energy as the hot utility source. The economics of the resulting solution is evaluated using net present value, and it was found that, to obtain a positive NPV, the stripping cost in the retrofitted network will have to be as low as possible, or annual operating cost of the non-retrofitted primary mass exchange network will have to be high.

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