Synthesis of pyrochlore-type La2Sn2O7@GO for the in-situ profiling of organophosphate pesticides paraoxon ethyl in environmental samples

Abstract

The detection and monitoring of organophosphate pesticides in environmental samples are of paramount importance due to their potentially harmful effects on human health and ecosystems. In this study, we present the detection of paraoxon ethyl (POE), a widely used organophosphate pesticide, utilizing an electrochemical method. We synthesized graphene oxide-incorporated pyrochlore-type lanthanum stannate (La2Sn2O7@GO) as a sensing material for enhanced detection sensitivity and selectivity. The electrochemical detection of POE was performed using a glassy carbon electrode modified with the synthesized nanocomposite. The modified electrode La2Sn2O7@GO/GCE exhibited a remarkable electrochemical response towards POE, showing a significant reduction potential and an increase in the peak current compared to the bare and other modified electrodes. The proposed electrochemical method showed excellent detection sensitivity and selectivity for POE, with a linear response range of concentrations from 0.01 to 360 μM and a low detection limit (LDL) of 2.73 nM. The sensor also exhibited good stability and reproducibility, making it a promising tool for practical pesticide detection applications. The developed sensor offers a cost-effective, sensitive, and reliable platform for the rapid monitoring of organophosphate pesticides in environmental samples, contributing to the advancement of pesticide detection technologies and environmental protection efforts.