Abstract

AbstractA series of pyrido[2,3‐d]pyrimidine‐4,7‐diones 5a‐h were prepared from 6‐amino‐4‐pyrimidones 1 and benzylidene Meldrum's acid derivatives 2 by cyclization reactions in boiling nitrobenzene. The structure of 5, determined by nmr measurements, reveals a selective orientation of 1 and 2 in the addition step.

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