Abstract
Anodic oxidation of a series 1,4-dihydropyridines were performed in acetonitrile-tetrabutylammonium perchlorate electrolyte solution at platinum electrode using controlled potential electrolysis. On the bases of electroanalytical results the electrochemical oxidation mechanism of 1,4-dihydropyridines could be designed ECEC process. As a result of two-electron oxidation corresponding pyridines were obtained in yields ranging from 85%–92%. The advantages of electrochemical synthesis of pyridine derivatives are simple reaction condition, low cost and of high purity products.
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