Abstract
The synthesis and ruthenium-catalyzed hydrosilylation reactions of 3-dimethylsilyl-2-ethynylpyridine derivatives (1a–1d) are described. The reaction of 1a and 1b in the presence of a ruthenium catalyst gave the corresponding pyridine-fused siloles (2a and 2b) through intramolecular hydrosilylation. The UV–Vis absorption and fluorescence properties of 2a and 2b were investigated, and DFT calculations were performed to understand their photophysical properties.
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