Abstract
A series of cyano (ligand) cobaloximes have been prepared where, the ligand is pyrazole (Pz), 1-(acetamido)pyrazole (Apz), 1-(N-methylacetamido)pyrazole (MAPz), l-(acetamido)-3,5-dimethylpyrazole (MADMPz). The complex K[(CN)Co(D 2 H 2 )SCN] reacts with ethanolic solution of pyrazole or pyrazole amido ligands to form mixed ligand complexes. In all these complexes, the pyrazoles act as monodentate ligands and bind to Co I I I through N-2 of pyrazole ring.
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