Abstract
Abstract In this work, the acid and photocatalytic properties of titanate nanotubes (NTs) were surveyed. The surface acidity of the NTs was characterized by FTIR with lutidine and pyridine. The photocatalytic degradation of phenol in aqueous suspension was performed to test the photocatalytic properties of the NTs. The results were compared with those obtained from commercial TiO 2 . NTs were prepared by hydrothermal treatment of TiO 2 nanoparticles in a NaOH aqueous solution. During the washing step, three different acid agents (HCl, H 2 SO 4 , and HNO 3 ) were used. TiO 2 nanoparticles were synthesized previously by the sol-gel method. The photocatalytic materials were characterized by FTIR, XRD, XPS, S BET , UV–vis, and HRTEM. It was found that the used acid agent significantly affected the amount and type of acid sites. Bronsted acid sites were favored by the use of HNO 3 . Lewis acid sites were promoted when HCl was employed during the washing step, which is in contrast with the results obtained using the other acids chosen in this work. Besides, the use of HCl promoted the H 2 Ti 3 O 7 phase. The acid phase H 2 Ti 4 O 9 ·H 2 O was favored when HNO 3 was used and H 2 SO 4 formed the H 2 Ti 2 O 4 ·(OH) 2 acid phase. The presence of Cl, S, and N species on the NTs was not found. Furthermore, Na + ions were completely removed from the surface of the NTs, which were exchanged by H + ions. It was found, in general, that the three catalysts presented a relatively high photocatalytic activity to remove phenol. However, NTs washed with HNO 3 (NT-HNO 3 ) displayed the best photocatalytic activity compared to the other NTs. After 200 min, NT-HNO 3 reached a phenol degradation yield close to 100%. Commercial TiO 2 presented a phenol degradation yield close to 60%. It could be concluded that the acid phase (H 2 Ti 4 O 9 ·H 2 O) and concentration of Bronsted acid sites promoted the photocatalytic activity of NT-HNO 3 .
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