Abstract

The free base 2,4-bis-(1′-dodecynyl)-deuteroporphyrin IX dioctylester, 6a, its Zn(II)complex, Zn- 6a, its Cu(II)complex, Cu- 6a, its Ni(II)complex, Ni- 6a and a number of related compounds have been prepared. The synthesis of 6a involves as key steps the palladium-catalyzed coupling of β-diiodoporphyrin with dodecyne, and the acid-catalyzed esterification of the two propionic acid groups of deuteroporphyrin with n-octanol.

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