Abstract
The synthesis of conjugated polymers with controlled stereoregularity and molecular weight has been widely studied. Recently, application to block copolymers has been developed, and conjugated polymers with various functions have been reported. As increased attention is given to organic magnetic materials as next-generation synthetic metals, we synthesized chiral magnetic block copolymers with a polythiophene backbone with high stereoregularity in this study. A phenoxy radical was introduced into one side chain as a magnetic block. In addition, a chiral substituent was introduced into the other side chain as a chiral block. The block copolymer synthesized in this study has high stereoregularity in both the chiral and magnetic blocks. In addition, a one-handed chiral aggregation is formed due to the influence of the chiral substituent. Furthermore, magnetic measurements indicate that phenoxy radicals are generated and may imply antiferromagnetism. Based on the spectroscopic data, a chiral magnetic material with high stereoregularity was successfully synthesized.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
