Abstract
The synthesis of a new class of phosphazene polymers through the thermal ring-opening polymerization of the cyclotriphosphazene gem-(NPCl 3 ) 2 N 3 P 3 Cl 4 (1), is reported. The resultant polymer possesses controlled short-chain branching sites along the phosphazene backbone. The chlorine atoms in this polymeric intermediate were replaced by organic side groups to yield novel organic-inorganic polymers that are stable to ambient conditions
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