Abstract
The first phenylmagnesium carboxylates, C 6H 5MgOOCR·THF, have been made by reaction of phenylmagnesium bromide with the sodium salt of carboxylic acids [RCOONa {where R = CH 3, ClCH 2, Cl 2CH, Cl 3C, CH 3CH 2, (CH 3) 2CH, C 6H 5CH 2 and CH 3(CH 2) 3CH 2}]. All these derivatives are white or pale yellow solids, soluble in polar solvents. The carboxylates have been characterized by elemental analysis, conductance measurements, and spectral studies ( 1H NMR and IR). The IR data suggest that carboxylate group acts as a bridging bidentate ligand.
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