Abstract
Advanced polymer structures are gaining traction in the coatings industry where they may, for instance, give rise to antifouling and anti-icing surfaces. With a focus on industrial feasibility, a series of copolymers from poly(dimethylsiloxane) monomethacrylate (PDMSMA), methoxy poly(ethylene glycol) monomethacrylate (MPEGMA) and methyl methacrylate (MMA) were prepared via reverse iodine transfer polymerization (RITP) and reversible complexation mediated polymerization (RCMP). Using inexpensive materials and synthesis approaches scalable for larger industrial quantities, a variety of (amphiphilic) copolymers and block copolymers were prepared. Compared to semi-batch free-radical polymerization (FRP), the RITP/RCMP approaches resulted in higher conversions of the macromonomers, lower polymer dispersities, allowed synthesis of block copolymers, as well as being simpler than most other common RDRP techniques.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.