Abstract
Pd nanocatalysts based on cucurbit[n]uril were successfully synthesized by an operationally simple one-pot liquid-phase method using different reducing agents. Through changing the reducing agents and the ratio of feedstock, well-defined Pd nanostructures with various shapes were obtained. The results of morphological analysis demonstrate that cucurbit[6]uril plays a key role in guiding the formation of Pd nanostructures, and is responsible for the Suzuki and Heck coupling reactions with high efficiency.
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