Abstract
The formation of precipitation under the action of a direct current atmospheric pressure discharge in air on an iron sulfate (II) solution, which was the cathode and anode, was studied. As turbidimetric kinetics measurements have shown, the process, which proceeds both in the cathode and in the anode, has two stages. At the first stage (slow), a colloidal solution is formed, which then (the second stage, faster) is destroyed with the formation of a flocculent precipitate. The characteristic process times for both stages were found depending on the discharge current, the increase of which led to an increase in the deposition rate. The deposition rate in the cell with a liquid cathode was higher than in the cell with a liquid anode. For this reason, the amount of precipitate formed in the cell with the liquid cathode was greater than in the cell with the liquid anode at the same treatment time. Particle sizes of colloidal solutions and sediments were determined by scanning electron microscopy and dynamic light scattering . The sizes of both colloidal particles and sediment particles for the liquid anode were significantly smaller than for the liquid cathode. X-ray diffraction analysis showed that the precipitations obtained are amorphous, and their calcination turns them into γ-Fe2O3. Based on the data of elemental analysis and others, the composition of micelles was proposed, which included Fe(OH)3, SO4–, and H2O. An analysis of the mechanisms of the processes showed that the most probable chain of transformations involves the oxidation of Fe2+ by HO2 and H2O2 molecules to Fe3+, which irreversibly reacts with OH– to form Fe(OH)3.
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