Abstract

1. When a mixture of cyclopentadiene and trichlorosilane is heated for a short time in a flow apparatus at 550° and atmospheric pressure, trichloro-2-cyclopenten-1-ylsilane is formed. The same compound is formed also in the liquid-phase catalytic reaction between cyclopentadiene and trichlorosilane. 2. A new method is proposed for the preparation of trichlorocyclopentadienylsilane by the pyrolysis of trichloro(2,3-dichlorocyclopentyl)silanes.

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