Abstract
Alkynyl anilines react with a diketo open-cage fullerene derivative and expand the orifice size from 11- to 18-membered rings. Benzyl azide reacts with the terminal alkynyl group under Click conditions. Single crystal X-ray structure of the C s symmetric bis-3-alkynylaniline derivative showed the formation of a head to tail dimer due to strong H-bonding and π-π interactions.
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