Abstract
In the synthesis of offretite, tetramethylammonium (TMA) cations are preferentially located in the gmelinite cages. Additional TMA cations, monoethanolamine or 1,2-diaminoethane molecules are then needed to ensure that the linear channels of the offretite are maintained. However, when either MEA or DAE is used, stricter adherence to the optimum synthesis conditions is necessary to avoid excess alkali in the product. The substitution of either MEA or DAE for TMA leads to different crystallite morphologies.
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