Abstract
The novel, highly blue, fluorescent N-methyl-6,11-dimethoxybenzo[2,3-b]carbazole derivatives were prepared by oxidative coupling of anilines with naphthoquinone followed by palladium catalyzed oxidative CH functionalization and a one pot reductive methylation reaction. The benzocarbazole fluorophores were photophysically characterized and the effects of the substituents investigated. (TD)-DFT calculations faithfully reproduced experimental photophysical properties of the benzocarbazoles and revealed how the substituents affect the photophysical properties of these compounds.
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