Synthesis of novel polyaryl(ether-ketones) withtert-butyl pendent groups

Abstract

Linear polyaryl(ether ketones) containing tert-butyl pendent groups were prepared from aromatic hydrocarbons and aromatic diacid chlorides, both classes of monomers containing tert-butyl pendent groups. The polymers were prepared in high yield and high molecular weight by low-temperature precipitation polycondensation in 1,2-dichloroethane. The presence of meta-oriented moieties and bulky pendent groups played a beneficial role with regard to solubility, while the thermal transitions and thermal resistance were not greatly impaired relative to conventional all para-oriented polyaryl(ether-ketones). The current polyaryl(ether-ketones) showed glass transition temperatures in the range 170-240°C and decomposition temperatures, as measured by TGA, of about 500°C.