Abstract
Reactions of the organo(silyl)phosphine (e.g., Me/sub 3/SiPR/sub 2/ and (Me/sub 3/Si)/sub 2/PR) with alkenes in benzene or toluene at 85/sup 0/C followed by hydrolysis with excess deoxygenated H/sub 2/O are reported to occur cleanly and yield organophosphorus and organophosphorus-metal compounds. /sup 31/P, /sup 13/C, and /sup 1/H NMR spectra are reported for the products. The phosphines prepared by this method are characterized directly and in some cases by hydrolysis derivatization to the related primary or secondary phosphines.
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