Synthesis of Novel (Meth)acrylates with Variable Hydrogen Bond Interaction and Their Application in a Clear Viscoelastic Film.

Abstract

Clear viscoelastic films (CVFs) have many applications in the display industry. Acrylic monomers containing a hydrogen bond (H-monomer) are often used in the preparation of CVF to increase the cohesion and form favorable interactions with the display substrate. Common H-monomers face a counterbalance between the glass transition temperature (Tg) and the hydrogen-bonding association constant (Ka). Strong hydrogen bonding often leads to a high Tg and high modulus, which are unfavorable in certain applications such as foldable display. To solve these problems, four types of hydrogen-bonding (meth)acrylic monomers (carbamate acrylate, carbamate methacrylate, urea acrylate, and urea methacrylate) with different Ka and Tg were readily synthesized. Among them, urea acrylates displayed the highest Ka while still maintaining moderate Tg. These H-monomers were copolymerized with 2-ethylhexyl acrylate (EHA) and cross-linked to obtain a series of copolymers (H-copolymers) as pressure-sensitive adhesives. After the characterization of rheology, optics, and peel adhesion, urea-acrylic H-copolymers showed the best overall performance by combining great optical property (>98% in transmittance, < 1% in haze) and mechanical performance (8-12 N/25 mm in peel adhesion, 84-92% in creep recovery). This work provides a new path to prepare acrylic CVF for flexible display application.