Abstract
A family of novel ferrocenylphosphine–amidine ligands derived from ( R)-( S)-PPFNH 2-R 5 was applied to the palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenylprop-2-en-1-yl acetate 8a or pivalate 8b with dimethyl malonate. Up to 94% e.e. was achieved when ligand 6b was used.
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