Abstract
Novel chitosan-based adsorbent materials with a higher fatty diacid diglycidyl as the crosslinking agent were synthesized and the adsorption abilities of the resulting polymers evaluated towards typical acid dyes. The successful formation of a crosslinked structure was confirmed via infrared spectroscopic measurements and the solubility of the polymer towards 10% aqueous solutions of acetic and formic acids determined. At higher dye concentrations, the adsorption abilities of the crosslinked chitosan towards hydrophilic CI Acid Orange 7 and CI Acid Red 1 increased with decreasing degree of substitution. However, at lower dye concentrations, the crosslinked chitosan with the lowest degree of substitution exhibited the lowest adsorption capability. With such hydrophilic acid dyes, the extent of adsorption decreased significantly as the pH of the solution increased. On the other hand, CI Acid Red 138, which contains a dodecyl group in the chemical structure, was adsorbed to a considerable extent even at higher pH values, suggesting hydrophobic interaction between the alkyl group in the dye molecule and the hydrophobic crosslinker.
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