Abstract

A variety of N-heterocyclic carbene (NHC) complexes of general formula fac-[Mn(NHC)(CO)3(bipy)]+ have been prepared by reaction of the manganese(I) isocyanide complexes fac-[Mn(CNR)(CO)3(bipy)]+ with propargylamines and propargylic alcohols and characterized by spectroscopic and X-ray diffraction methods.

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