Abstract
The irradiation with UV light at - 12°C of the neutral complexes fac-[Mn(CN)(CO) 3(NN)] (NN bipyridine, or 4,4′-dimethylbipyridine) in the presence of L P(OR) 3 (R Me, Et or Ph) in CH 2Cl 2 gave the neutral monocarbonyls of formula trans-[Mn(CN)(CO)(NN)L 2]. These complexes reacted with MeI and KPF 6 in THF at room temperature to give the new cationic methyl-isocyanide monocarbonyls trans-[Mn(CNMe)(CO)(NN)L 2]PF 6.
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