Abstract
The irradiation with UV light at - 12°C of the neutral complexes fac-[Mn(CN)(CO) 3(NN)] (NN bipyridine, or 4,4′-dimethylbipyridine) in the presence of L P(OR) 3 (R Me, Et or Ph) in CH 2Cl 2 gave the neutral monocarbonyls of formula trans-[Mn(CN)(CO)(NN)L 2]. These complexes reacted with MeI and KPF 6 in THF at room temperature to give the new cationic methyl-isocyanide monocarbonyls trans-[Mn(CNMe)(CO)(NN)L 2]PF 6.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.