Abstract
This paper reports de synthesis of a series of (-)-menthylalkyltin dihydrides, (-)-MenRSnH2 (R = Me, n-Bu, i-Pr, t-Bu, Neophyl), starting from (-)-menthyltrimethyltin. The new (-)-menthylalkyltin dihydrides 12–16 were used in a study on the stereoselective reduction of chiral (-)-menthone under different reaction conditions. Also the results obtained in the reductions of prochiral acetophenone (27) and 2-acetylnaphthalene (28), with (-)-menthylmethyl- (12) and (-)-menthyli-propyltin (14) dihydrides are informed. Some physical properties as well as full 1H-, 13C-, and 119Sn NMR data of the new organotin compounds are informed.
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