Synthesis of needle-like aragonite from limestone in the presence of magnesium chloride

Abstract

Needle-like aragonite was synthesized with a reversible solution reaction from limestone without calcinations. Scan Electron Microscope (SEM) and X-ray Diffraction (XRD) were used to characterize the morphology and the crystal structure of aragonite. The synthesis of aragonite whisker involves two steps. At first GCC (Ground Calcium Carbonate) was dissolved in an aqueous solution of magnesium chloride with reflux and air flush. Then CO 2 was bubbled into the suspension at a low temperature to produce aragonite whisker. An in-house designed reactor and acid–base titration analysis were used to measure the remaining GCC content in the reaction mixture. A kinetics equation of GCC dissolution was developed, which showed a first-order kinetic feature to magnesium chloride concentration. A reaction rate constant of 0.04234 h −1 was obtained. The dissolution rate of GCC in magnesium chloride is much higher than that in the magnesium sulfate solution. Some aragonite whiskers with a length of ca. 20 μm and an aspect ratio of 8–12 can be synthesized.