Synthesis of nanosized spinel ferrites MnFe2O4 on the surface of carbon nanotubes for the creation of polymer composites with enhanced microwave absorption capacity

Abstract

Currently, the creation of new protective materials able to absorb the electromagnetic (EM) radiation is an important direction strongly linked to the use of high-tech electronics which leads to EM pollution in a wide range of high frequencies. The wide-band absorption and large bandwidth are two important factors affected the absorbing performance of materials. In this research, the development of polymer nanocomposites based on the multi-walled carbon nanotubes (CNTs) as a conductive component modified by manganese ferrite (MnFe2O4) nanoparticles as a magnetic component made it possible to increase the efficiency of absorption of EM waves in the frequency range 1–41 GHz as a result of good impedance matching characteristics in comparison with pure manganese ferrite. Finally, the absorption coefficient of EM waves in the frequency range of 5–20 GHz for MnFe2O4/0.065 vol.%CNT nanocomposites about 2.5–3 times higher than for MnFe2O4. The present work shows, that the introduction of MnFe2O4/CNT composites into the both amorphous (epoxy resin) and crystalline (polychlorotrifluoroethylene) polymer matrices makes it possible to manage microwave absorbing properties as well as a shift of the region of frequencies of maximum peak values of the absorption coefficient and reflection loss. The obtained relations prove that by the change of the amount of the modifying component (MnFe2O4) on the surface of carbon nanotubes, the content of the MnFe2O4/CNT nanocomposite in the polymer matrixes, and the thickness of the polymer composites it is possible to control the absorption coefficient and reflection loss of EM waves in the high frequency range. The MnFe2O4/0.044CNT–PCTFE and MnFe2O4/0.065CNT–epoxy resin composites exhibit higher bandwidth in relation to other reported composites or structures at the same thickness.