Abstract
The N,C-dilithiated product 1 of 2-allylphyrrole was prepared and studied by 7Li NMR in THF/HMPTA. Compound 1 reacts selectively in THF with electrophiles (H 2O, Mel, Me 3SiCl) to give the Z-isomers 2a–4a. In diethylether, the analogous reactions lead selectively to the E-isomers 2b–4b.
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