Abstract

AbstractMultifunctional 3‐amino‐4‐dialkylphosphono‐2‐quinolinones have been prepared by “one‐pot” nucleophilic addition and regioselective ring enlargement of imino isatins. The addition reaction between imino isatins and dialkyl (diazomethyl)phosphonate proceeds smoothly using potassium carbonate as a catalyst, and a subsequent regioselective ring expansion promotes by salicylic acid to afford the desired products in high yields.magnified image

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