Abstract
A stepwise synthesis of mixed monodentate bis-NHC complexes of Ir(I), employing Ag(I)NHC complexes as transfer agents, yields complexes with two monodentate NHCs having different steric and electronic characteristics. The crystal structure of the mixed complex ( 5) with both a triazole-derived NHC ligand and an imidazole-derived NHC ligand is reported and both the NHC ring geometry and the M–NHC bond lengths are similar to related complexes. The complexes maintain their integrity over time and do not disproportionate, consistent with the NHC ligands not being labile.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.