Abstract
Abstract Carbon disulfide is known to undergo “insertion reactions” with various nitrogen-carbon bonds,1 nitrogentrivalent phosphorus bonds,2 nitrogen-trivalent arsenic bonds,1,3 nitrogen-silicon bonds,1,4 nitrogen-transition metal bonds and nitrogen-sulfur bonds.6,7,8 The reaction of carbon disulfide with secondary amine sulfides or alkyl sulfenamides furnished tetralkyl thiuram disulfides6 and trithiopercarbamates,7,8 respectively (Eq. I and II).
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