Abstract

AbstractSummary: Macroporous monoliths consisting of silica nanoparticles embedded in poly(methyl methacrylate) (PMMA) were synthesized in supercritical CO2. Well‐dispersed silica particles, pretreated with functional 3‐(trimethoxysilyl)propyl methacrylate (MPS), were to form colloidal PMMA nanocomposites followed by a sol‐gel transition forming interconnected structures resulting in micron‐sized pores with specific areas between 1 and 7 m2 · g−1. SEM and TEM results revealed uniform morphological characteristics of the composite materials and good dispersions of the silica nanoparticles.SEM micrograph of PMMA/Silica nanocomposites forming interconnected macroporous monolith. The average size of the silica particles is 50 nm.imageSEM micrograph of PMMA/Silica nanocomposites forming interconnected macroporous monolith. The average size of the silica particles is 50 nm.

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