Abstract

The aldol condensation of 3-furaldehyde and enol silanes or enolates(Li,Mg and Ti) of 2,6-dimethyl- and 2,2,6-trimethylcyclohexanones has been investigated.The lithium enolate of 2,6-dimethylcyclohexanone showed good facial and diastereoselectivity as did the magnesium enolate of 2,2,6-trimethylcyclohexanone.These results were applied to the preparation of limonoid model compound by a short and selective route

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