Abstract
New poly(pyrimido[5,4- d]pyrimidine-2,6-diyl) (PPympym) with bulky dialkylamino substituents (–NR 2, R=hexyl, decyl) was prepared by organometallic dehalogenative polycondensation using a zerovalent Ni complex. The obtained PPympym was soluble in common organic solvents such as CHCl 3 and THF, and GPC analysis (in CHCl 3; vs. polystyrene standards) indicated that new Ppympyms had high number-average molecular weights M n of 19,100–34,000; they also gave a high [ η] value of about 2.1 dl g −1. PPympym showed strong photoluminescence both in CHCl 3 and in film, and greenish-blue electroluminescence from PPympym-based double-layer light-emitting devices (ITO/PEDOTh/PPympym/Ca–Al; PEDOTh, poly(ethylenedioxythiophene)) was observed.
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